Wikia

PlanetStar Wiki

Gibbium

Comments0
171pages on
this wiki
Gibbium (164Gb)
Nomenclature
Pronunciation /'gi•bē•(y)üm/
Name in Saurian Warraim (Wr)
/'wōr•rām/
Systematic name Unhexquadium (Uhq)
/'ün•heks•kwo•dē•(y)üm/
Location on the periodic table
Period 8
Coordinate 7d10
Above element Copernicium (112Cn)
Below element ––
Previous element Keplerium (163Kp)
Next element Pasturium (165Ps)
Family Zinc family
Series Vanthoffide series
Atomic properties
Atomic mass 478.9781 u, 795.3618 yg
Atomic radius 111 pm, 1.11 Å
Van der Waals radius 181 pm, 1.81 Å
Subatomic particles 639
Nuclear properties
Nucleons 475 (164 p+, 311 n0)
Nuclear ratio 1.90
Nuclear radius 9.32 fm
Half-life 3.0228 min
Electronic properties
Electron notation 164-8-24
Electron configuration [Mc] 5g18 6f14 7d10 8s2 8p2
2, 8, 18, 32, 50, 32, 18, 4
Oxidation states 0, +2, +4, +6
(mildly basic oxide)
Electronegativity 1.73
First ionization energy 684.1 kJ/mol, 7.090 eV
Electron affinity 18.6 kJ/mol, 0.193 eV
Covalent radius 122 pm, 1.22 Å
Physical properties
Bulk properties
Molar mass 478.978 g/mol
Molar volume 10.455 cm3/mol
Density 45.812 g/cm3
Atomic number density 5.76 × 1022 cm−3
Average atomic separation 259 pm, 2.59 Å
Speed of sound 3211 m/s
Magnetic ordering Diamagnetic
Crystal structure Simple hexagonal
Color Brownish gray
Phase Solid
Thermodynamics
Melting point 1007.67 K, 734.52°C
1354.13°F, 1813.80°R
Boiling point 1668.56 K, 1395.41°C
2543.74°F, 3003.41°R
Liquid range 660.89 K/°C, 1189.60°F/°R
Liquid ratio 1.66
Triple point 1007.63 K, 734.48°C
1354.07°F, 1813.74°R
@ 1.8744 Pa, 0.014059 torr
Critical point 4875.47 K, 4602.32°C
8316.17°F, 8775.84°R
@ 401.9154 MPa, 3966.609 atm
Heat of fusion 9.116 kJ/mol
Heat of vaporization 176.136 kJ/mol
Heat capacity 0.05757 J/g/K, 0.10363 J/g/°R
27.577 J/mol/K, 49.638 J/mol/°R
Abundance
Universe (by mass) Relative: 2.07 × 10−37
Absolute: 6.93 × 1015 kg

Gibbium is the fabricated name of a hypothetical element with the symbol Gb and atomic number 164. Gibbium was named in honor of Josiah Willard Gibbs (1839–1903), who pioneered chemical thermodynamics and one of the founders of statistical mechanics. This element is known in scientific literature as unhexquadium (Uhq), dvi-mercury, or simply element 164. Gibbium is the heaviest member of the zinc family (below zinc, cadmium, mercury, and copernicium) and is the last member of the vanthoffide series; this element is located in periodic table coordinate 7d10. Despite it is a d-block element, it is the last period 8 element.

Properties Edit

Physical Edit

Gibbium is a soft, brownish gray metal with a density of 45.8 g/cm3, twice as high as the lighter cogener copernicium (23.7 g/cm3). Like zinc and cadmium, gibbium forms hexagonal crystal lattices. Gibbium has the poor conductor of heat but a fair conductor of electricity.

For lighter cogeners, melting and boiling points decrease with increasing atomic numbers, but due to the element's ability to covalently bond with each other due to hybridization of electrons in the 8p1/2 orbital, it actually has the highest melting and boiling points of any other zinc family elements. The melting point of 735°C is in stark comparison with mercury (−39°C) and copernicium (−112°C). As a result, gibbium is solid like family members zinc and cadmium. Due to their phase points, gibbium requires more energy to melt and boil this element than any of the other family members. One mole of gibbium requires 919 kJ to liquify, and give off that same amount when solidifying. One mole of liquid gibbium requires 17617 kJ to vaporize, and give off that same amount when condensing.

The triple point is almost identical to its melting point, but at a pressure of 1.87 pascals. Triple point is a point on the phase diagram where all three states of matter are allowed to exist. Liquid gibbium would be nonexistent at any temperature below the triple point. On the other side of it is critical point, a minimum where liquid and gas would be indistinguishable. For a copper family member, gibbium has the highest critical point temperature (4602°C), but the second lowest in critical point pressure (402 megapascals).

Atomic Edit

Hence its atomic number, gibbium contains 164 protons, in addition to those that makeup the nucleus, there are also 311 neutrons that help stabilize the nucleus against the repulsive forces of protons. Nuclear ratio, which is the neutron/proton ratio, is 1.90. Since protons carry positive charge, the atom should have a charge of +164, but actually it is neutral because it contains 164 electrons, which carry negative charge of same degree as protons. This element has completed a 7d orbital, consistent with its place on the periodic table, however it contains two electrons in the 8p orbital due to relativistic effects.

Isotopes Edit

Like every other elements heavier than lead, gibbium has no stable isotopes. The most stable isotope is 475Gb with a half-life of roughly 3 minutes. It undergoes spontaneous fission, splitting into two or three lighter nuclei as well as neutrons like the following example.

475
164
Gb → 208
82
Pb + 114
48
Cd + 80
34
Se + 73 1
0
n

The second longest lived isotope, 479Gb, has a half-life of 47 seconds. The third longest lived isotope, 477Gb, has a half-life of 17 seconds. The fourth longest lived isotope, 473Gb, has a half-life of 9 seconds. All of the remaining isotopes have half-lives less than 2 seconds while majority of these have half-lives of less than 80 milliseconds. There are also a few metastable isomers including couple long-lived, the most stable being 475m1Gb with a half-life of nearly four months and 471m2Gb with a half-life of more than a month.

Chemical Edit

Gibbium has four possible oxidation states: 0, +2, +4 and +6 with +6 the most dominant. With the electronegativity of 1.73 and first ionization energy 7.09 eV, gibbium shows some chemical activities like lighter cogeners such as zinc and mercury. In aqueous solutions, Gb2+ (light red) is the most stable cation, followed by Gb4+ (light blue) and Gb6+ (peach).

Compounds Edit

Gibbium(IV) oxide (GbO2) is an olive green powder in contrast to gibbium(VI) oxide (GbO3) being a dark purple powder. Gibbium(IV) sulfide (GbS2) is a sky blue amorphous solid while gibbium(VI) sulfide (GbS3) is a pink amorphous solid. Gibbium can readily react with halogens such as fluorine and bromine. The examples of gibbium halides are GbF4, GbF6, and GbBr2. Gibbium(II) bromate (Gb(BrO3)2) forms when bromide and oxide react together with excess oxygen at high temperature.

GbO2 + GbBr4 + 5 O2 → 2 Gb(BrO3)2

Gibbium(II) fulminate (Gb(CNO)2) is brownish red powder when a gibbium oxide combines with cyanogen. The fulminate can react with excess hydrogen sulfide to form gibbium thiocyanate (Gb(SCN)2), which is a pale pink powder.

Gb(CNO)2 + 2 H2S → Gb(SCN)2 + 2 H2O

Gibbium thiocyanate can be decomposed to gibbium cyanide (Gb(CN)2) and is then treated with dilute sulfuric acid to form gibbium dithiazyl (Gb(SN)2) and an exotic acid called percarbonic acid.

Gb(CN)2 + 2 H2SO4 → Gb(SN)2 + 2 H2CO4

Alternatively, Gb(CN)2 can be treated with sulfur dioxide to form a dark brown powder Gb(SN)2.

Gb(CN)2 + 2 SO2 → Gb(SN)2 + 2 CO2

Gb(SN)2 can be converted to a more stable Gb(SN)4 by reducing S4N4 to S2N2.

Gb(SN)2 + S4N4 → Gb(SN)4 + S2N2

Gibbium can form coordination complexes in addition to Gb(SN)2 and Gb(SN)4 by bonding to ligands in the 0 oxistate, like Gb(CO)4 and Gb(PF3)4. Gb(CO)4 is an organogibbium compound along with examples like tetramethyl orthogibbate (GbC4H12O4).

Occurrence and synthesis Edit

It is almost certain that gibbium doesn't exist on Earth at all, but it is believed to exist somewhere in the universe, at least in very tiny amounts. Since every element heavier than lithium were produced by stars, then gibbium must be produced in stars, and then thrown out into space by exploding stars. But it is theoretically impossible for even the most powerful supernovae or most violent neutron star collisions to produce this element through r-process because there's not enough energy available or not enough neutrons, respectively, to produce this heavy element. Instead, this element virtually can only be made by advanced technological civilizations. An estimated abundance of gibbium in the universe by mass is 2 × 10−37, which amounts to 6.93 × 1015 kilograms.

To go along with other such civilizations, humans on Earth may eventually have the capability to synthesize gibbium. To synthesize most stable isotopes of gibbium, nuclei of a couple lighter elements must be fused together, and right amount of neutrons must be seeded. This operation would be extremely difficult since it requires vast amounts of energy and even if nuclei of this element were produced would immediately decay due to its brief half-life. Here's couple of example equations in the production of the most stable isotope 475Gb.

209
83
Bi + 205
81
Tl + 61 1
0
n → 475
164
Gb
287
109
Mt + 133
55
Cs + 55 1
0
n → 475
164
Gb
Periodic table
1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18
1 H He
2 Li Be B C N O F Ne
3 Na Mg Al Si P S Cl Ar
4 K Ca Sc Ti V Cr Mn Fe Co Ni Cu Zn Ga Ge As Se Br Kr
5 Rb Sr Y Zr Nb Mo Tc Ru Rh Pd Ag Cd In Sn Sb Te I Xe
6 Cs Ba La Ce Pr Nd Pm Sm Eu Gd Tb Dy Ho Er Tm Yb Lu Hf Ta W Re Os Ir Pt Au Hg Tl Pb Bi Po At Rn
7 Fr Ra Ac Th Pa U Np Pu Am Cm Bk Cf Es Fm Md No Lr Rf Db Sg Bh Hs Mt Ds Rg Cn Bc Fl Lz Lv J Mc
8 Nw Gl * Du Bu Ab Sh Hi Da Bo Fa Av So Hr Wt Dr Le Vh Hk Ke Ap Vw Hu Fh Ma Kp Gb
9 Ps Hb Kf Bn Ju Hm Bs Rs
* Ls Dm Ms Ts Dt Mw Pk By Bz Fk Dw To Pl Ah My Cv Fy Ch An Ed

Around Wikia's network

Random Wiki